2,667 research outputs found

    An unrealistic image of science

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    Many UK secondary schools (ages 11-18) host Open Days for pupils in their final year of primary school education (age 10). At these events science teachers try, through the judicious use of a select number of practical tasks, to portray science as being a fun, exciting and essentially a „hands on‟ activity. Whilst this approach generates short-term situational interest amongst pupils it is ultimately an unrealistic, and arguably unsustainable, image of science

    Acute hypertensive cardiac failure in pregnancy

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    On nonlinear viscoelastic deformations - a reappraisal of Fung's quasilinear viscoelastic model

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    This article offers a reappraisal of Fung's method for quasilinear viscoelasticity. It is shown that a number of negative features exhibited in other works, commonly attributed to the Fung approach, are merely a consequence of the way it has been applied. The approach outlined herein is shown to yield improved behaviour, and offers a straightforward scheme for solving a wide range of models. Results from the new model are contrasted with those in the literature for the case of uniaxial elongation of a bar: for an imposed stretch of an incompressible bar, and for an imposed load. In the last case, a numerical solution to a Volterra integral equation is required to obtain the results. This is achieved by a high order discretisation scheme. Finally, the stretch of a compressible viscoelastic bar is determined for two distinct materials: Horgan-Murphy and Gent

    Non-exponential relaxation and hierarchically constrained dynamics in a protein

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    A scaling analysis within a model of hierarchically constrained dynamics is shown to reproduce the main features of non-exponential relaxation observed in kinetic studies of carbonmonoxymyoglobin.Comment: 4 pages, 3 figures in text. Reference errors have been correcte

    Near IR luminescent rare earth 3,4,5,6-tetrafluoro-2-nitrophenoxide complexes: Synthesis, X-ray crystallography and spectroscopy

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    NOTICE: this is the author’s version of a work that was accepted for publication in Near IR luminescent rare earth 3,4,5,6-tetrafluoro-2-nitrophenoxide complexes: Synthesis, X-ray crystallography and spectroscopy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Near IR luminescent rare earth 3,4,5,6-tetrafluoro-2-nitrophenoxide complexes: Synthesis, X-ray crystallography and spectroscopy, [VOL27, ISSUE5, (2008)] DOI: 10.1016/j.poly.2008.01.02

    Complete remission of diabetes mellitus during pregnancy

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    Acute Renal Failure Following Intravenous Cholangiography

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    A case of acute renal failure following the diagnostic administration of a tri-iodinated compound is reported. The clinical findings and course are presented, with particular emphasis on the fact that there appeared to be no underlying or associated disorder which may have cause the renal failure, other than possible mild dehydration.S. Afr. Med. J., 45, 1400 (1971

    Determining phase transitions of layered oxides via electrochemical and crystallographic analysis

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    The chemical diffusion coefficient in LiNi1/3Mn1/3Co1/3O2 was determined via the galvanostatic intermittent titration technique in the voltage range 3 to 4.2 V. Calculated diffusion coefficients in these layered oxide cathodes during charging and discharging reach a minimum at the open-circuit voltage of 3.8 V and 3.7 V vs. Li/Li+, respectively. The observed minima of the chemical diffusion coefficients indicate a phase transition in this voltage range. The unit cell parameters of LiNi1/3Mn1/3Co1/3O2 cathodes were determined at different lithiation states using ex situ crystallographic analysis. It was shown that the unit cell parameter variation correlates well with the observed values for chemical diffusion in NMC cathodes; with a notable change in absolute values in the same voltage range. We relate the observed variation in unit cell parameters to the nickel conversion into the trivalent state, which is Jahn-Teller active, and to the re-arrangement of lithium ions and vacancies
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